Diphenyl (o-tolylamido)phosphonate

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Diphenyl (o-tolyl­amido)­phospho­nate

The asymmetric unit of the title compound, C(19)H(18)NO(3)P, contains two independent mol-ecules in which the P atoms are found in slightly distorted tetrahedral environments. In the crystal, pairs of inter-molecular N-H⋯O(P) hydrogen bonds form two independent centrosymmetric dimers.

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Bis(diphenyl-p-tolyl­phosphane-κP)(2-hy­droxy-3,5,7-bromo­cyclo­hepta-2,4,6-trienonato-κ2 O,O′)copper(I)

The Cu(I) atom in the title compund, [Cu(C(7)H(2)Br(3)O(2))(C(19)H(17)P)(2)], is located on a twofold rotation axis; the 3,5,7-tribromo-tropolonate anion coordinates as a bidentate ligand with a bite angle of 76.42 (9)°. An intra-molecular C-H⋯O inter-action occurs. Within the crystal, extensive weak C-H⋯π inter-actions contribute to the herringbone pattern observed in the packing of the mol-ec...

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trans-Bis(4,7-diphenyl-1,10-phenanthroline-κ2 N,N′)bis­(nitrato-κ2 O,O′)zinc(II)

The title compound, [Zn(NO(3))(2)(C(24)H(16)N(2))(2)], is a twofold axially symmetric coordination compound. Given that the Zn-O interactions [2.4926 (15) and 2.6673 (15) Å] can be considered as weakly bonding and the nitrate ions share the same C(2) axis of the Zn(dpp)(2) fragment (dpp is 4,7-diphenyl-1,10-phenanthroline), these anions belong to the coordination sphere of Zn(2+), leading to a ...

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Diphenyl chloro­thio­phospho­nate

The complete mol-ecule of the title compound, C(12)H(10)ClO(2)PS, is generated by crystallographic mirror symmetry, with the P, S and Cl atoms lying on the mirror plane. The resulting PO(2)SCl tetra-hedron is significantly distorted [O-P-O = 96.79 (9)°]. The crystal packing exhibits no directional inter-actions.

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[Determination of diphenyl and o-phenylphenol in agricultural products by GC/MS].

A simple determination method of diphenyl (DP) and o-phenylphenol (OPP) in agricultural products by GC/MS was examined. DP and OPP were extracted with ethyl acetate in the presence of anh. sodium sulfate. After addition of n-butanol, the extract solution was concentrated. Clean-up was achieved by shaking with graphitized bulk carbon (Supelclean ENVI-Carb). Addition of polyethylene glycol sharpe...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811013924